internal treatment system must be used to control these materials. Looking at the first item, dissolved oxygen control,. target values specified by most manufacturers and utilities have called for oxygen concentrations in boiler feedwater or closed heating/cooling
Sodium carbonate partially breaks down at high temperature to sodium hydroxide (caustic) and carbon dioxide. High temperatures in the boiler water reduce the solubility of calcium sulphate and tend to make it precipitate out directly on the boiler metal as scale.
2018/9/1 · Typical damage to any carbon-steel materials, including piping, boiler tubes and drums, will include pitting and thinning of the components due to the oxygen attacking the iron in the carbon steel (Figure 1). This pitting is a result of the basic reaction for the formation of rust (Equations (1) and (2)). 4Fe + 6H 2 O + 3O 2 → 4Fe (OH) 3 (1)
2 Methods of boiler internal scale control 2.1 Carbonate control Before the acceptance of phosphate treatment in the 1930's, calcium sulphate scaling was a major boiler problem. Sodium carbonate treatment was used to precipitate calcium as calcium carbonate to
1999/4/25 · Hollander, Orin. "Control of Sodium to Phosphate Ratio in Real Time in a Boiler in the Presence of Additives and Impurities." Paper presented at the CORROSION 99, San Antonio, Texas, April 1999. Download citation file: Ris (Zotero) Reference Manager EasyBib
Boiler system pH/phosphate program control method - NALCO CHEMIC…
A pH/phosphate program in a boiler water system is controlled by: (1) determining the feed rate of the phosphate to the boiler by adding to a phosphate-feed stream containing the phosphate feeding to the boiler a phosphate-feed tracer in known proportion to the
2016/5/25 · Measured sodium concentrations cannot be used in calculating sodium-to-phosphate ratios for control of boiler water pH because measured sodium concentrations include non-phosphate sodium salts. While dissolved sodium chloride and sulfate do not …
1999/11/1 · The U.S. Department of Energy's Office of Scientific and Technical Information OSTI.GOV Conference: Control of sodium to phosphate ratio in real time …
2019/2/1 · Congruent phosphate uses a sodium-to-phosphate ratio of 2.6:1 with increased phosphate level. Cycling units and boilers with substantial waterside deposits must operate with reduced phosphate
2015/9/15 · Phosphate/Polymer Treatment Boiler Control Parameters • Phosphate residual as PO4 depending on hardness in the feedwater • usually associated with boiler pressure • and environmental legislation • M alkalinity of 700 ppm as CaCO3 (25 % of TDS) • Polymer : min
What is claimed is: 1. A method for monitoring and/or controlling pH, phosphate concentration and sodium to phosphate ratio in a boiler system using captive alkalinity, comprising the steps of: a) determining the phosphate concentration of said system by using
2011/3/13 · Control of Sodium to Phosphate Ratio in Real Time in a Boiler in the Presence of Additives and Impurities CORR99 A Review Of Long-Term Exposure Of …
2015/5/13 · For much of the past century, sodium-phosphate based boiler-water treatments have been used to buffer pH and to control scale in industrial and electric power utility drum boilers. Phosphate "hideout" is characterized by the retention of phosphate in the boiler during conditions of high operating temperatures, and its subsequent release when the operating temperature is reduced.
4 Total carryover of sodium is determined as the ratio of the saturated steam sodium concentration to boiler water sodium concentration. Mechanical carryover is determined by subtracting the vaporous sodium carryover in the steam at high pressures. T = Cs / Cb * 100 (1)
Boiler system pH/phosphate program control method Download PDF Info Publication number EP0640747B1 EP0640747B1 EP94113074A EP94113074A EP0640747B1 EP 0640747 B1 EP0640747 B1 EP 0640747B1 EP 94113074 A EP94113074 A EP Prior art
Boiler feedwater systems using demineralized or evaporated makeup or pure condensate may be protected from caustic attack through coordinated phosphate/pH control. Phosphate buffers the boiler water, reducing the chance of large pH changes due to the development of high caustic concentrations.
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